Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate - Names and Identifiers
Name | Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
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Synonyms | 5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE Bis(acetonitrile)(cyclooctadiene)rhodium tetrafluoroborate Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluorob... Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate acetonitrile,(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
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CAS | 32679-02-0
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Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate - Physico-chemical Properties
Molecular Formula | C12H14BF4N2Rh
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Molar Mass | 375.97 |
Appearance | solid |
Color | yellow |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Sensitive | Air Sensitive |
Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate - Risk and Safety
Hazard Symbols | Xi - Irritant
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Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin.
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Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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WGK Germany | 3 |
TSCA | No |
Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate - Introduction
Bis(acetonitril) (1,5-cycloctadiene) rhodium(I) tetrafluoroborate is a chemical complex with the formula [Rh(C2H3N)2(C8H12)] Bf4. The following is a description of some properties, uses, preparation and safety information about this compound:
Nature:
- Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a yellow solid.
-It is insoluble in water, but soluble in organic solvents such as ethanol, acetone and dimethylformamide.
-It is stable to light and air, and has high stability at room temperature.
Use:
- Bis(acetonitril)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is an important catalyst, which is widely used in a variety of organic synthesis reactions. For example, it is commonly used in hydrogenation, reduction and carbonylation reactions.
-It also has applications for asymmetric catalytic reactions.
Method:
-Generally, the method of preparing Bis(acetonitril) (1,5-cycloctadiene) rhodium(I) tetra fluoroborate is to combine rhodium pentachloride with an excess of 1, reaction of 5-cyclooctadiene and acetonitrile.
-After the reaction is completed, the obtained product can be extracted by crystallization or other purification methods.
Safety Information:
- Bis(acetonitril)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate is a toxic compound that needs to be operated under closed laboratory conditions.
-Avoid direct contact with skin and eyes when handling this compound.
-When using or storing, avoid contact with flammable materials, and keep away from high temperature and open fire.
-Use personal protective equipment such as protective gloves and safety glasses when performing operations.
Last Update:2024-04-10 22:29:15